ETH Zurich / Energy Turnaround A step towards cheap aluminum batteries

Die Forschenden stellten im Labor Aluminium-Knopfbatterien her. Das Batteriegehäuse ist aus Edelstahl, das innen mit Titannitrid beschichtet ist, um es korrosionsbeständig zu machen.
The researchers ofETH Zurich and Empa produced aluminium button cells in the laboratory. The battery case is made of stainless steel coated with titanium nitride on the inside to make it corrosion resistant.

The energy turnaround depends on technologies that allow the inexpensive temporary storage of electricity from renewable sources. With titanium nitride and polypyrene scientists from ETH Zurich and Empa have found two new materials that can lead to low-cost aluminum batteries.

Although existing lithium-ion batteries are ideal for electromobility due to their low weight, they are also quite expensive and therefore unsuitable for economical large-scale, stationary power storage. Furthermore, lithium is a relatively rare metal and is hard to extract – unlike aluminum, magnesium or sodium. Batteries based on one of the latter three elements are thus seen as a promising option for stationary power storage in the future. However, such batteries are still at the research stage and have not yet entered industrial use.

A promising new candidate is aluminum batteries, which are made from cheap and abundant raw materials. But as the electrolyte fluid in aluminum batteries is extremely aggressive and corrodes stainless steel, and even gold and platinum, scientists are searching for corrosion-resistant materials for the conductive parts of these batteries.

Scientists from ETH Zurich and Empa – led by Maksym Kovalenko, Professor of Functional Inorganic Materials – have found what they are looking for in titanium nitride, a ceramic material that exhibits sufficiently high conductivity. “This compound is made up of the highly abundant elements titanium and nitrogen, and it’s easy to manufacture,” explains Kovalenko.

The scientists have successfully made aluminum batteries with conductive parts made of titanium nitride in the laboratory. The material can easily be produced in the form of thin films, also as a coating over other materials such as polymer foils. Kovalenko believes it would also be possible to manufacture the conductors from a conventional metal and coat them with titanium nitride, or even to print conductive titanium nitride tracks on to plastic. “The potential applications of titanium nitride are not limited to aluminum batteries. The material could also be used in other types of batteries; for example, in those based on magnesium or sodium, or in high-voltage lithium-ion batteries,” says Kovalenko.

Polypyrene instead of graphite

The second new material can be used for the positive electrode (pole) of alumnium batteries. Whereas the negative electrode in these batteries is made of alumnium, the positive electrode is usually made of graphite. Now, Kovalenko and his team have found a new material that rivals graphite in terms of the amount of energy a battery is able to store. The material in question is polypyrene, a hydrocarbon with a chain-like (polymeric) molecular structure. In experiments, samples of the material – particularly those in which the molecular chains congregate in a disorderly manner – proved to be ideal. “A lot of space remains between the molecular chains. This allows the relatively large ions of the electrolyte fluid to penetrate and charge the electrode material easily,” Kovalenko explains.

One of the advantages of electrodes containing polypyrene is that scientists are able to influence their properties, such as the porosity. The material can therefore be adapted perfectly to the specific application. “In contrast, the graphite used at present is a mineral. From a chemical engineering perspective, it cannot be modified,” says Kovalenko.

As both titanium nitride and polypyrene are flexible materials, the researchers believe they are suitable for use in “pouch cells” (batteries enclosed in a flexible film).

References

Walter M, Kravchyk KV, Böfer C, Widmer R, Kovalenko MV: Polypyrenes as High-Performance Cathode Materials for Aluminum Batteries. Advanced Materials 2018, 1705644, doi: 10.1002/adma.201705644

Wang S, Kravchyk KV, Filippin AN, Müller U, Tiwari AN, Buecheler S, Bodnarchuk MI, Kovalenko MV: Aluminum Chloride‐Graphite Batteries with Flexible Current Collectors Prepared from Earth‐Abundant Elements. Advanced Science 2018, 1700712, doi: 10.1002/advs.201700712